Title of article
Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride
Author/Authors
Shen، نويسنده , , Shu-Su and Kartika، نويسنده , , Vita and Tan، نويسنده , , Ying Shan and Webster، نويسنده , , Richard D. and Narasaka، نويسنده , , Koichi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
5
From page
986
To page
990
Abstract
In the presence of copper(I) chloride, tert-butyl 1-hydroxy-2-methyl-6-trifluoromethyl-1H-indole-3-carboxylate acted as a catalyst for the chemoselective aerobic oxidation of allylic and benzylic alcohols. A variety of primary and secondary allylic and benzylic alcohols were oxidized into the corresponding α,β-unsaturated carbonyl compounds in good yields without affecting non-allylic alcohols.
Keywords
Allylic alcohol , Benzylic alcohol , Selective aerobic oxidation , N-Hydroxyindole
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1880164
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