Author/Authors :
Fuchter، نويسنده , , Matthew J. and Weimar، نويسنده , , Marko and Yang، نويسنده , , Xuezheng and Judge، نويسنده , , Dilraj K. and White، نويسنده , , Andrew J.P.، نويسنده ,
Abstract :
En route to helicene metal ‘sandwich’ complexes we have discovered an unusual oxidative rearrangement of [7]-helicene. The process involves a substantial skeletal rearrangement with the loss of helicity. We describe the identification of this curious product and its subsequent characterisation data.
Keywords :
helicene , Diels–Alder , Rearrangement , fragmentation
