Title of article
Catalyst-free transformations of diethyl 2-ethoxymethylenemalonate and diethyl polyfluorobenzoylmalonates in water
Author/Authors
Bazhin، نويسنده , , Denis N. and Kudyakova، نويسنده , , Yulia S. and Burgart، نويسنده , , Yanina V. and Saloutin، نويسنده , , Victor I.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
3
From page
1961
To page
1963
Abstract
The unusual transformation of diethyl 2-ethoxymethylenemalonate into triethyl 1,3,5-benzenetricarboxylate is described. This one-pot reaction proceeds in water without any catalyst in a good yield. One of the proposed intermediates of this process is also used under similar conditions to give the desired trisubstituted benzene. A catalyst-free, efficient, practical, and convenient process in water based on deethoxycarbonylation has been developed to form ethyl polyfluorobenzoylacetates in a high yield from diethyl polyfluorobenzoylmalonates.
Keywords
water chemistry , cyclotrimerization , Dealkoxycarbonylation , ?-keto esters
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1880494
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