Title of article :
Nitrone formation in phosphate buffer and aqueous solutions: novel chemistry inspired by a natural product
Author/Authors :
Pansanit، نويسنده , , Acharavadee and Ingavat، نويسنده , , Nattha and Aree، نويسنده , , Thammarat and Mahidol، نويسنده , , Chulabhorn and Ruchirawat، نويسنده , , Somsak and Kittakoop، نويسنده , , Prasat، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
Nitrones are formed from the reaction of aspergillusol A (1) and a ketone/aldehyde in phosphate buffer and aqueous solutions with pH ranges of 6.8–8.6, resembling physiological conditions. The reaction of 1 with 1-substituted cyclohexanones gave the (1′S∗,2′R∗)-isomer, diastereoselectively.
Keywords :
nitrone , Reaction in aqueous solution , green chemistry , reaction in water , natural products
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
