Title of article
A Lewis acid-promoted reduction of acylsilanes to α-hydroxysilanes by diethylzinc
Author/Authors
Gao، نويسنده , , Guang and Bai، نويسنده , , Xing-Feng and Li، نويسنده , , Fei and Zheng، نويسنده , , Long-Sheng and Zheng، نويسنده , , Zhan-Jiang and Lai، نويسنده , , Guo-Qiao and Jiang، نويسنده , , Kezhi and Li، نويسنده , , Fuwei and Xu، نويسنده , , Li-Wen، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
3
From page
2164
To page
2166
Abstract
We report here the first example of the reduction of acylsilanes to α-hydroxysilanes, in which diethylzinc was used as a highly reactive agent in the presence of Ti(OiPr)4 or other Lewis acids. The reduction typically proceeds to give synthetically useful α-hydroxysilanes in good yields.
Keywords
Organosilicon chemistry , Reduction , Diethylzinc , Lewis acid , silane
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1880585
Link To Document