Title of article :
Generation of benzofuroxans by photolysis of crystalline o-nitrophenylazides. A green chemistry reaction
Author/Authors :
Leyva، نويسنده , , Elisa and Gonzلlez-Balderas، نويسنده , , Regina M. and de Loera، نويسنده , , Denisse A. and Jiménez-Cataٌo، نويسنده , , Rogelio، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
Several benzofuroxans were obtained by photolysis of crystalline o-nitrophenylazides at ambient temperature. In this particular case, the solid matrix favored the elimination of nitrogen and exclusive formation of heterocyclic benzofuroxan. However, this reaction gives quantitative yields only with crystalline o-nitrophenylazides with a high melting point (above 50 °C).
Keywords :
green chemistry , Benzofuroxans , o-Nitrophenylazide , Photochemistry in crystals
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
