Title of article
Catalytic enamines from dialkylamide-dialkylacetals
Author/Authors
Davey، نويسنده , , Roger M. and Stamford، نويسنده , , N. Patrick J. Stamford، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
3
From page
2537
To page
2539
Abstract
The formation of a transient enamine derived from DMF-DMA provides an effective alternative to the harsh conditions normally required for the nucleophilic addition of base-activated methylene compounds to a carbonyl group. Organocatalysts formed from dialkylamide-dialkylacetals in this manner may provide extensive synthetic utility for a number of well-established reactions in which the formation of enolates and enamines has been employed.
Keywords
organocatalyst , carbonyl , Enamine , Reaction Mechanism , Hann–Lapworth reaction
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1880732
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