Title of article :
Formal synthesis of (−)-stemoamide using a useful epimerization at C-8
Author/Authors :
Chavan، نويسنده , , Subhash P. and Harale، نويسنده , , Kishor R. and Puranik، نويسنده , , Vedavati G. and Gawade، نويسنده , , Rupesh L.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
The formal synthesis of (−)-stemoamide was achieved starting from l-pyroglutamic acid. The key steps used are the allylation using BF3·OEt2, ring closing metathesis, allylic oxidation and a novel epimerization at C8.
Keywords :
allylation , allylic oxidation , pyroglutamic acid , Stemoamide , Ring closing metathesis
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
