Title of article
An efficient total synthesis of calothrixin B
Author/Authors
Bhosale، نويسنده , , Shrikar M. and Gawade، نويسنده , , Rupesh L. and Puranik، نويسنده , , Vedavati G. and Kusurkar، نويسنده , , Radhika S.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
3
From page
2894
To page
2896
Abstract
An efficient synthesis of calothrixin B (2) is demonstrated starting from 9H-carbazol-4-ol, having two one-pot reaction sequences as key steps. As a novel observation, DMF–methanol was shown to be a hydride donor for reduction of aldehyde to alcohol. Unexpectedly, nucleophilic substitution of benzyloxy by methoxy group was observed.
Keywords
CAN , DMF–methanol , Hydride donor , Calothrixin B
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1880888
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