Title of article :
Highly diastereoselective addition of allyltitanocenes to α-chiral ketones
Author/Authors :
Takeda، نويسنده , , Takeshi and Yoshida، نويسنده , , Satoshi and Nishimura، نويسنده , , Takuya and Tsubouchi، نويسنده , , Akira، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
The addition of allyltitanium reagents, generated by the desulfurizative titanation of allylic sulfides with the titanocene(II) reagent Cp2Ti−1-butene, to α-chiral ketones produced tertiary homoallylic alcohols bearing three adjacent chiral centers with high diastereoselectivity.
Keywords :
allylation , Allylic sulfides , Homoallylic alchols , chiral ketones , diastereoselectivity
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
