Title of article
Highly diastereoselective addition of allyltitanocenes to α-chiral ketones
Author/Authors
Takeda، نويسنده , , Takeshi and Yoshida، نويسنده , , Satoshi and Nishimura، نويسنده , , Takuya and Tsubouchi، نويسنده , , Akira، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
3930
To page
3933
Abstract
The addition of allyltitanium reagents, generated by the desulfurizative titanation of allylic sulfides with the titanocene(II) reagent Cp2Ti−1-butene, to α-chiral ketones produced tertiary homoallylic alcohols bearing three adjacent chiral centers with high diastereoselectivity.
Keywords
allylation , Allylic sulfides , Homoallylic alchols , chiral ketones , diastereoselectivity
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1881318
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