Title of article :
Oxidative transformation of azides to aryl nitriles using DIB/TBHP: scope and mechanistic insights
Author/Authors :
Zhao، نويسنده , , Ying-Yi and Chew، نويسنده , , Xinying and Leung، نويسنده , , Gulice Y.C and Yeung، نويسنده , , Ying-Yeung and Corey، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
Bis(tert-butylperoxy)iodobenzene, generated in situ by the reaction between diacetoxyl iodobenzene (DIB) and tert-butyl hydroperoxide (TBHP), was used in the oxidative transformation of primary azides to nitriles, and secondary azides to ketones.
Keywords :
Oxidation , hypervalent iodine , Nitrile , Selectivity , Mechanism
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
