Title of article
Reductive etherification of aldehydes photocatalyzed by dicarbonyl pentamethylcyclopentadienyl iron complexes
Author/Authors
Argouarch، نويسنده , , Gilles and Grelaud، نويسنده , , Guillaume and Roisnel، نويسنده , , Thierry and Humphrey، نويسنده , , Mark G. and Paul، نويسنده , , Frédéric، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
4
From page
5015
To page
5018
Abstract
The reductive etherification of aldehydes can be performed by the reaction with dialkylmethylsilanes in the presence of new iron(II) piano-stool catalysts of general formula Cp∗Fe(CO)2Ar (Cp∗ = η5-C5Me5; Ar = Ph, 4-C6H4OCH3, 4-C6H4CH3, Fc). This transformation is promoted by UV light and affords a simple route for the preparation of unsymmetrical alkyl ethers.
Keywords
Piano-stool complexes , reductive etherification , Silanes , Iron catalysis
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1881919
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