Title of article
Novel sequential 1,4-Brook rearrangement–Wittig reaction: new one-pot approach for silyl dienol ethers
Author/Authors
Matsuya، نويسنده , , Yuji and Koiwai، نويسنده , , Azusa and Minato، نويسنده , , Daishiro and Sugimoto، نويسنده , , Kenji and Toyooka، نويسنده , , Naoki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
3
From page
5955
To page
5957
Abstract
A novel one-pot synthetic method of silyl dienol ethers via 1,4-Brook rearrangement–Wittig reaction sequence has been developed. This tandem reaction proceeded via the intramolecular silyl migration step, which enabled stereoselective formation of phosphorane intermediates. The reaction is operationally simple and high yielding, thus providing a new useful formula for silyl dienol ether synthesis.
Keywords
Silyl dienol ether , 1 , 4-Brook rearrangement , Wittig reaction , Tandem reaction
Journal title
Tetrahedron Letters
Serial Year
2012
Journal title
Tetrahedron Letters
Record number
1882533
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