Title of article :
Ferrocene tagged functional polymer: a robust solid-phase reagent for O-demethylation
Author/Authors :
Kurane، نويسنده , , Rajanikant and Gaikwad، نويسنده , , Vipul and Jadhav، نويسنده , , Jagannath and Salunkhe، نويسنده , , Rajashri and Rashinkar، نويسنده , , Gajanan، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
Ferrocene tagged functional polymer was synthesized by exploiting the propensity of the Merrifield resin to undergo quaternization with N-ferrocenylmethyl benzimidazole followed by subsequent anion metathesis reaction. The synthesized polymer when employed as a solid-phase reagent for O-demethylation of aryl methyl ethers, showed TON in the range of 7373–8930 and TOF in the range of 279–494 h−1.
Keywords :
Functional polymer , Ferrocene , o-Demethylation , Reusability , Merrifield resin
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
