Title of article
A supramolecular amphiphile from a new water-soluble calix[5]arene and n-dodecylammonium chloride
Author/Authors
Gattuso، نويسنده , , Giuseppe and Notti، نويسنده , , Anna and Pappalardo، نويسنده , , Andrea and Pappalardo، نويسنده , , Sebastiano and Parisi، نويسنده , , Melchiorre F. and Puntoriero، نويسنده , , Fausto، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
188
To page
191
Abstract
A new water-soluble calix[5]arene 1, bearing 4-butylsulfonato pendant groups at the lower rim, has been synthesised. This derivative shows aggregation properties in water. Critical micellar concentration (cmc) for 1 has been calculated by means of DOSY NMR and fluorescence spectroscopy. When n-dodecylammonium chloride is added to 1 below its cmc, the resulting 1:1 endo-cavity inclusion complex behaves as a supramolecular amphiphile providing a new micellar aggregate.
Keywords
Supramolecular amphiphile , DOSY , Calixarene , Micelle , Sulfonato group
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1883335
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