Author/Authors :
Medru?، نويسنده , , Ili?ca and Turdean، نويسنده , , Raluca and Gropeanu، نويسنده , , Radu and Pop، نويسنده , , Flavia and Toupet، نويسنده , , Loïc and H?dade، نويسنده , , Niculina D. and Bogdan، نويسنده , , Elena and Grosu، نويسنده , , Ion، نويسنده ,
Abstract :
New phenothiazine macrocycles with polyethyleneoxy chains were synthesized in good yields by reacting 10-ethyl-10H-3,7-di(3-hydroxyphenyl)phenothiazine with diiodurated or ditosylated polyethyleneglycols. Their structures were investigated by NMR spectroscopy and single crystal X-ray crystallography in the case of one compound. The electronic properties were determined by absorption spectroscopy and cyclic voltammetry and their complexation ability for alkali cations was investigated by ES-HRMS.
Keywords :
phenothiazines , Macrocycles , X-ray molecular structure , C–H?? interactions , ES-HRMS investigations
