Title of article :
Allylation of aldehydes with potassium allyltrifluoroborate catalyzed by lanthanide-based metal-organic framework
Author/Authors :
Freitas، نويسنده , , Juliano C.R. and de Oliveira، نويسنده , , Cristiane K. and Cunha، نويسنده , , Edilanio C. and Malvestiti، نويسنده , , Ivani and Alves Jr.، نويسنده , , Severino and Longo، نويسنده , , Ricardo L. and Menezes، نويسنده , , Paulo H.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Pages :
4
From page :
1558
To page :
1561
Abstract :
The use of the framework [Eu2(fum)3(H2O)4]·(3H2O), Eu-MOF, as catalyst for allylation of aldehydes by potassium allyltrifluoroborate is described. The method features the use of small catalyst loads and wet solvents, and the products were obtained in high yields, short reaction times, at room temperature with no further purification. The catalyst was recovered and reused up to six times in further allylation reactions without significant loss in the yields.
Keywords :
allylation , MOF catalysis , Potassium organotrifluoroborates
Journal title :
Tetrahedron Letters
Serial Year :
2013
Journal title :
Tetrahedron Letters
Record number :
1884012
Link To Document :
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