Title of article :
Artificial enzyme activity from cyclodextrins with cyanohydrins on the secondary rim
Author/Authors :
Zhou، نويسنده , , You and Pedersen، نويسنده , , Christian M. and Bols، نويسنده , , Mikael، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
The synthesis of two per-O-methylated cyclodextrins with one or two α-hydroxypropionitrile groups attached to the secondary rim is described. The two new cyanohydrins are found to catalyse the hydrolysis of 4-nitrophenyl β-D-glucopyranoside in a buffer solution at pH 8.0 with a rate acceleration of up to 1770.
Keywords :
cyclodextrin , Catalysis , General acid , Glycosidase , Chemzymes
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
