Title of article :
Selective reduction of acyl aziridines to Mannich bases using silyllithium reagents
Author/Authors :
Davis، نويسنده , , Amanda L. and Korous، نويسنده , , Arthur A. and Hartel، نويسنده , , Aaron M.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
Mannich bases are prepared from the selective α-reduction of acyl aziridines using silyllithium reagents. The reaction proceeds via an aziridine ring-opening assisted Brook rearrangement.
Keywords :
Reduction , Silyllithium , Mannich base , Brook rearrangement , aziridine
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters