Title of article
Surprising behavior of NXO-peptides toward the lithium hydroxide solvolysis
Author/Authors
Khan، نويسنده , , Farhan A. and Rabong، نويسنده , , Constantin and Jordis، نويسنده , , Ulrich and Phopase، نويسنده , , Jaywant، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
3679
To page
3682
Abstract
An unexpected rearrangement of NXO peptides was observed during solvolysis of the methyl ester using lithium hydroxide as the base. It was found that the NXO-compounds rearranged into semioxamazide derivatives in which the ester is derived from the alcohol used as the reaction solvent.
Keywords
NXO-building blocks , L-phenylalanine , Modified amino acids , Rearrangement , Peptidomimetics
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1884904
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