Title of article
Synthesis of unsymmetrical polyfluorinated diaryl sulfides by rhodium-catalyzed aryl exchange reaction
Author/Authors
Arisawa، نويسنده , , Mieko and Ichikawa، نويسنده , , Takuya and Yamaguchi، نويسنده , , Masahiko، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
4327
To page
4329
Abstract
RhH(PPh3)4 and 1,2-bis(diphenylphosphino)benzene (dppBz) catalyze the aryl exchange reaction of polyfluorinated diaryl sulfides. By employing these catalysts, unsymmetrical polyfluorinated diaryl sulfides are synthesized by the reaction of symmetrical polyfluorinated diaryl sulfides and substituted pentafluorobenzenes in the presence of triisopropylsilane.
Keywords
Unsymmetrical polyfluorinated diaryl sulfides , Aryl exchange reaction , Symmetrical polyfluorinated diaryl sulfides , Rhodium catalyst , Pentafluorobenzenes
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1885177
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