Title of article :
Direct conversion of glycerol into formic acid via water stable Pd(II) catalyzed oxidative carbon–carbon bond cleavage
Author/Authors :
Pullanikat، نويسنده , , Prasanna and Lee، نويسنده , , Joo Ho and Yoo، نويسنده , , Kyung Soo and Jung، نويسنده , , Kyung Woon، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
Using our tridentate NHC-amidate–alkoxide Pd(II) complex, we developed a catalytic method for oxidative C–C bond cleavage of glycerol. The glycerol was degraded exclusively to formic acid and CO2. Two possible degradation pathways were proposed through 13C labeled studies.
Keywords :
Degradation of glycerol , Formic acid , Oxidative catalysis , NHC amidate ligand , palladium catalyst
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
