Author/Authors :
Ghosh، نويسنده , , Subhash Chandra and Ngiam، نويسنده , , Joyce S.Y. and Seayad، نويسنده , , Abdul M. and Tuan، نويسنده , , Dang Thanh and Johannes، نويسنده , , Charles W. and Chen، نويسنده , , Anqi، نويسنده ,
Abstract :
A tandem process for the oxidative amidation of benzyl alcohols with amine hydrochloride salts has been developed using inexpensive Fe(NO3)3 as the catalyst, air and aqueous t-butyl hydroperoxide as oxidants. A wide range of benzamides have been synthesized under mild conditions. This greener amide formation method provides an economical and practical assess to benzamides from readily available and inexpensive starting materials.
Keywords :
Oxidative amidation , benzyl alcohol , Amides , Tandem oxidation , Iron(III) nitrate
