Title of article
Facile synthesis of C-phosphanylformamidines via a carbene pathway
Author/Authors
Marchenko، نويسنده , , Anatoliy and Koidan، نويسنده , , Georgyi and Hurieva، نويسنده , , Anastasiya and Savateev، نويسنده , , Aleksandr N. Kostyuk، نويسنده , , Aleksandr، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
5671
To page
5673
Abstract
A direct synthetic approach to C-phosphanyl-N,N-dialkyl-N′-aryl(alkyl)-formamidines was developed. It was shown that phosphorylation of the formamidines proceeds at the nitrogen atom affording N-phosphanylformamidinium salts. Upon deprotonation, these salts gave C-phosphanylformamidines via formation of carbenes followed by a 1,2-phosphorus shift.
Keywords
C-Phosphanylformamidines , N-Phosphanylformamidinium triflates , Phosphanylation , Deprotonation
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1886313
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