Title of article
Substituent effects on the amination of racemic allyl carbonates using commercially available chiral rhodium catalysts
Author/Authors
Atallah، نويسنده , , Timothy and Blankespoor، نويسنده , , Ronald L. and Homan، نويسنده , , Philip and Hulderman، نويسنده , , Chase and Samas، نويسنده , , Brian M. and Van Allsburg، نويسنده , , Kurt and Vrieze، نويسنده , , Derek C.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
5795
To page
5798
Abstract
In the presence of commercially available chiral rhodium catalysts, a competitive benzylamination of racemic allyl carbonates, substituted with p-X-Ph groups, shows that the reaction proceeds faster with substituents (X) that are more electron-withdrawing. Mechanistic implications of these results are discussed.
Keywords
Rhodium-catalyzed , Hammett plot , Competitive substitution , Allylic benzylamination
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1886361
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