Title of article
Selective formation of non-conjugated olefins by samarium(II)-mediated elimination/isomerization of allylic benzoates
Author/Authors
Schaefer، نويسنده , , Sara L. and Roberts، نويسنده , , Connor L. and Volz، نويسنده , , Erasmus O. and Grasso، نويسنده , , Monika R. and O’Neil، نويسنده , , Gregory W.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
6125
To page
6128
Abstract
Aromatic allylic benzoates can be selectively transformed to the corresponding benzoate eliminated olefin by the action of samarium diiodide. Depending on the substrate and the elimination conditions, high selectivity for the non-conjugated alkene product can be achieved.
Keywords
elimination , Non-conjugated , Isomerization , Samarium
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1886521
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