Title of article
Manganese(III)-mediated oxidative radical addition of malonates to 2-cyanoindoles
Author/Authors
Lopchuk، نويسنده , , Justin M. and Montgomery، نويسنده , , William L. and Jasinski، نويسنده , , Jerry P. and Gorjifard، نويسنده , , Sayeh and Gribble، نويسنده , , Gordon W.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
6142
To page
6145
Abstract
2-Cyanoindole and N-methyl-2-cyanoindole undergo manganese(III)-mediated radical addition with activated methylene and methine compounds. Products of the methylene addition underwent additional oxidation during the course of the reaction to furnish the corresponding acetoxy compounds. Several structures were confirmed by X-ray crystallography.
Keywords
Captodative effect , Manganese(III) oxidation , Malonate , radical addition , 2-Cyanoindole
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1886536
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