Title of article :
Recyclable gallium(III) triflate-catalyzed [4+3] cycloaddition for synthesis of 2,4-disubstituted-3H-benzo[b][1,4]diazepines
Author/Authors :
Huang، نويسنده , , Shi-Gang and Mao، نويسنده , , Haifeng and Zhou، نويسنده , , Shao-Fang and Zou، نويسنده , , Jian-Ping and Zhang، نويسنده , , Wei، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
Simple and efficient Ga(OTf)3-catalyzed [4+3] cycloaddition of 1,3-diarylpropynones and o-phenylenediamines is developed for the preparation of 2,4-disubstituted-3H-benzo[b][1,4]diazepines. The reaction has advantages of using a green solvent, generating a minimal amount of waste, and easy catalyst recycle.
Keywords :
Catalysis , Ga(OTf)3 , 1 , 3-Diarylpropynones , 2 , 4]diazepines , 3 Cycloaddition
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters