Title of article
Expanding the scope of the indium-promoted allylation reaction: 4-(bromomethyl)-1,3-dioxol-2-one as a synthetic equivalent of a 3-arylhydroxyacetone enolate
Author/Authors
Bigovic، نويسنده , , Miljan and Skaro، نويسنده , , Sanja and Maslak، نويسنده , , Veselin and Saicic، نويسنده , , Radomir N.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
3
From page
6624
To page
6626
Abstract
Cyclic enol carbonates of type 2, obtained via the indium-promoted allylation of aldehydes with 4-(bromomethyl)-1,3-dioxol-2-one, undergo Heck reaction with aryl iodides in the presence of silver trifluoroacetate, to give the corresponding arylated products. Thus, 4-(bromomethyl)-1,3-dioxol-2-one can be considered as a synthetic equivalent of 3-arylhydroxyacetone enolate.
Keywords
Indium , Heck reaction , aldol reaction , organic synthesis , allylation
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1886806
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