Author/Authors :
Yang، نويسنده , , Hai-Tao and Ren، نويسنده , , Wen-Long and Dong، نويسنده , , Chun-Ping and Yang، نويسنده , , Yang and Sun، نويسنده , , Xiao-Qiang and Miao، نويسنده , , Chun-Bao، نويسنده ,
Abstract :
An efficient synthesis of fullerooxazoles was developed via PhI(OAc)2/I2-mediated [3+2] reaction of C60 with amides under photo-irradiation. The reaction was tolerant to various aryl and alkyl amides. The reaction mechanism was investigated in detail and a radical pathway was proposed for the formation of fullerooxazoles. Further transformation of compound 2l allowed the easy conjunction of fullerooxazole moiety to other molecular skeletons.
Keywords :
Fullerene , Amides , PhI(OAc)2 , iodine , Photo
