Title of article
Selective catalytic monoreduction of dichlorooligosilanes with Grignard reagents
Author/Authors
Kanno، نويسنده , , Ken-ichiro and Niwayama، نويسنده , , Yuka and Kyushin، نويسنده , , Soichiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
4
From page
6940
To page
6943
Abstract
Transition metal-catalyzed monoreduction of dichlorooligosilanes with Grignard reagents is reported. Among the examined catalysts, group 4 metal chlorides such as TiCl4 and Cp2TiCl2 gave the highest reactivity and good selectivity. The reducing power is effectively controlled by changing the catalysts and Grignard reagents to achieve sufficient selectivity depending on the oligosilane substrates.
Keywords
Oligosilane , Monoreduction , Grignard reagent , transition metal catalyst
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1886973
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