Title of article
Rhodium(III)-catalyzed ring-opening of strained olefins through C–H activation of O-acetyl ketoximes: an efficient synthesis of trans-functionalized cyclopentenes and spiro[2.4]heptenes
Author/Authors
Jijy and Varma، نويسنده , , E. and Prakash، نويسنده , , Praveen and Shimi، نويسنده , , M. and Saranya، نويسنده , , S. and Preethanuj، نويسنده , , P. and Pihko، نويسنده , , Petri M. and Varughese، نويسنده , , Sunil and Radhakrishnan، نويسنده , , K.V.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
5
From page
7127
To page
7131
Abstract
An efficient strategy for the stereoselective synthesis of functionalized cyclopentenes and spiro[2.4]heptenes from strained olefins via C–H activation of aryl ketone O-acetyl ketoximes using [RhCl2Cp∗]2 catalyst is described. The results revealed that a wide range of readily accessible aryl and heteroaryl ketoximes are compatible in this method for the ring opening of bicyclic and spirotricyclic olefins.
Keywords
Bicyclic olefin , C–H activation , ketoxime , Cyclopentene , Rhodium
Journal title
Tetrahedron Letters
Serial Year
2013
Journal title
Tetrahedron Letters
Record number
1887051
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