Title of article
Studies towards 1,3-diol units starting from syn β-hydroxy acylsilanes
Author/Authors
PavanKumar Reddy، نويسنده , , Gangireddy and Srirama Murthy، نويسنده , , Akondi and Satyanarayana Reddy، نويسنده , , J. and Das، نويسنده , , Saibal and Roisnel، نويسنده , , Thierry and Yadav، نويسنده , , Jhillu S. and Chandrasekhar، نويسنده , , Srivari and Grée، نويسنده , , René، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
365
To page
368
Abstract
Three complementary strategies have been explored to obtain stereodefined 1,3 diols starting from easily accessible syn β-hydroxy acylsilanes: fluoride induced migrations of substituents on silicon, a Grignard addition followed by protodesilylation and Tischenko-type reactions. Preliminary data on scope and limitations of these processes are presented.
Keywords
Acyl silanes , 1 , 3 Diols , aldol , Tischenko , Silicon
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1887528
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