Author/Authors :
PavanKumar Reddy، نويسنده , , Gangireddy and Srirama Murthy، نويسنده , , Akondi and Satyanarayana Reddy، نويسنده , , J. and Das، نويسنده , , Saibal and Roisnel، نويسنده , , Thierry and Yadav، نويسنده , , Jhillu S. and Chandrasekhar، نويسنده , , Srivari and Grée، نويسنده , , René، نويسنده ,
Abstract :
Three complementary strategies have been explored to obtain stereodefined 1,3 diols starting from easily accessible syn β-hydroxy acylsilanes: fluoride induced migrations of substituents on silicon, a Grignard addition followed by protodesilylation and Tischenko-type reactions. Preliminary data on scope and limitations of these processes are presented.
Keywords :
Acyl silanes , 1 , 3 Diols , aldol , Tischenko , Silicon
