• Title of article

    AsLn2, a luciferin-related modified tripeptide from the bioluminescent earthworm Fridericia heliota

  • Author/Authors

    Petushkov، نويسنده , , Valentin N. and Dubinnyi، نويسنده , , Maxim A. and Rodionova، نويسنده , , Natalja S. and Nadezhdin، نويسنده , , Kirill D. and Marques، نويسنده , , Simone M. and Esteves da Silva، نويسنده , , Joaquim C.G. and Shimomura، نويسنده , , Osamu and Yampolsky، نويسنده , , Ilia V.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2014
  • Pages
    3
  • From page
    463
  • To page
    465
  • Abstract
    AsLn2, an unusual modified peptide, was isolated from the bioluminescent earthworm Fridericia heliota (Enchytraeidae). Its structure, elucidated by NMR and mass spectrometry, includes residues of tyrosine, CompX (a novel tyrosine modification product, reported in the accompanying paper), and N(omega)-acylated lysine. Chromatography, UV, and 1H NMR data imply a close structural similarity of AsLn2 with F. heliota luciferin. AsLn2 appears to be an intermediate or by-product in F. heliota luciferin biosynthesis.
  • Keywords
    Bioluminescence , Fridericia heliota , luciferin , Modified peptide
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2014
  • Journal title
    Tetrahedron Letters
  • Record number

    1887621