Title of article :
Palladium-catalyzed asymmetric 1,6-addition of diphenylphosphine to (4-aryl-1,3-butadienylidene)bis(phosphonates) for the synthesis of chiral phosphines
Author/Authors :
Huang، نويسنده , , Jian and Zhao، نويسنده , , Mei-Xin and Duan، نويسنده , , Wei-Liang، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
An asymmetric 1,6-addition of diphenylphosphine to (4-aryl-1,3-butadienylidene)bis(phosphonates) catalyzed by a PCP pincer–Pd complex has been developed for the synthesis of chiral allylic phosphines with up to 91% ee under mild conditions.
Keywords :
Asymmetric 1 , 6-Addition , Pincer palladium catalyst , Bis(phosphonate)-substituted dienes , Chiral phosphines
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
