Title of article
Synthesis of the bicyclo[6.2.1]undecane ring system by a solvent-free Diels–Alder reaction
Author/Authors
Beatriz، نويسنده , , Adilson and Gomes، نويسنده , , Roberto da Silva and Constantino، نويسنده , , Mauricio Gomes and da Silva، نويسنده , , Gil Valdo José and de Oliveira، نويسنده , , Kleber Thiago، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
3
From page
679
To page
681
Abstract
A bicyclo[6.2.1]undecane model compound of the core structure of the biologically active furanoheliangolide sesquiterpene was synthesized. This new and short route was developed by using a solvent-free Diels–Alder reaction between cyclopentadiene and 3-nitro-2-cyclohexenone, followed by simple transformations. Theoretical calculations were performed in order to understand reactivity aspects of the cycloaddition.
Keywords
sesquiterpene , Diels–Alder , solvent-free , DFT calculations , Furanoheliangolide
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1887806
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