Title of article
Novel stereoselective synthesis of spiroketal structure using Pd(II)-catalyst
Author/Authors
Miyazawa، نويسنده , , Masahiro and Eizawa، نويسنده , , Toru and Yoshihara، نويسنده , , Shoko and Hatanaka، نويسنده , , Akinori and Yokoyama، نويسنده , , Hajime and Hirai، نويسنده , , Yoshiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
753
To page
756
Abstract
We report a highly stereoselective palladium(II)-catalyzed intramolecular cyclization of 1,11-dihydroxyundec-9-en-5-one derivatives via unstable hemiacetal intermediates, in which cyclization occurs without activation of the allylic alcohol to afford spiroketal structures.
Keywords
Dihydroxyketone , spiroketal , Palladium(II)-catalyst , hemiketal
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1887882
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