Author/Authors :
Shalamova، نويسنده , , Elena A. and Lee، نويسنده , , Yeosan and Chung، نويسنده , , Garam and Semakin، نويسنده , , Artem N. and Oh، نويسنده , , Jinho and Sukhorukov، نويسنده , , Alexey Yu. and Arkhipov، نويسنده , , Dmitry E. and Ioffe، نويسنده , , Sema L. and Semenov، نويسنده , , Sergey E.، نويسنده ,
Abstract :
A general strategy for the assembly of previously unknown tris(β,β,γ-oximinoalkyl)amines from aliphatic nitro compounds and methyl vinyl ketone is described. The strategy involves N,N-bis(siloxy)enamines as key intermediates. The latter are accessible by double silylation of alkylnitro compounds. Nickel(II) and copper(II) complexes of tris(β,β,γ-oximinoalkyl)amines are prepared and structurally characterized.
Keywords :
N , Michael addition , N-Bis(siloxy)enamines , Amines , oximes , ligands
