Title of article
Ruthenium(II)–NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols
Author/Authors
Wang، نويسنده , , Qingfu and Du، نويسنده , , Wangming and Liu، نويسنده , , Tingting and Chai، نويسنده , , Huining and Yu، نويسنده , , Zhengkun، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
1585
To page
1588
Abstract
Highly efficient Oppenauer-type oxidation of secondary alcohols to the corresponding ketones has been realized by means of the ruthenium(II) complex catalysts bearing a 2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine ligand. The oxidation reaction underwent in the presence of acetone as oxidant under mild conditions, reaching final TOF values up to 3960 h−1. The hemilability of the ligand is attributed to the high catalytic activity of these Ru(II) complexes.
Keywords
Ruthenium(II) , Oppenauer oxidation , Secondary alcohols , Pyridyl–imidazolyl–pyrazolyl ligand
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1888351
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