Title of article :
Ruthenium(IV) porphyrin catalyzed highly selective oxidation of internal alkenes into ketones with Cl2pyNO as terminal oxidant
Author/Authors :
Wang، نويسنده , , Zhi-Ming and Sang، نويسنده , , Xue-Ling and Che، نويسنده , , Chi-Ming and Chen، نويسنده , , Jian، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
A new method for the conversion of internal alkenes into ketones without cleavage of CC bond by using dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin [RuIV(TDCPP)Cl2] as catalyst and 2,6-dichloropyridine N-oxide(Cl2pyNO) as oxidant is developed.
Keywords :
Ketone , Alkene , N-oxide , Oxidation , Ruthenium porphyrin
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
