Author/Authors :
Hamada، نويسنده , , Shohei and Wada، نويسنده , , Yoshiyuki and Sasamori، نويسنده , , Takahiro and Tokitoh، نويسنده , , Norihiro and Furura، نويسنده , , Takumi and Kawabata، نويسنده , , Takeo، نويسنده ,
Abstract :
A method for oxidative kinetic resolution of racemic alcohols catalyzed by chiral nitroxyl radical (R,R)-1 has been developed. This method is especially effective for the kinetic resolution of tert-butyl aryl carbinols (s = up to 23).
Keywords :
kinetic resolution , Hydride shift , Oxidation , Nitroxyl radical , alcohols
