Title of article
Dynamic helicity control of single-helical oligooxime metal complexes by coordination of chiral carboxylate ions
Author/Authors
Osamu and Sairenji، نويسنده , , Shiho and Akine، نويسنده , , Shigehisa and Nabeshima، نويسنده , , Tatsuya، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
1987
To page
1990
Abstract
Helicity of single-helical metal complexes, [L1Zn3La]3+ and [L2Zn2La]3+, was dynamically controlled by coordination of chiral carboxylate ions such as mandelate ion. Spectroscopic investigation indicated that two chiral carboxylate ions contribute to the dynamic helicity control. In addition, the coordination of the carboxylate ions resulted in a nonlinear response in the dynamic helicity control.
Keywords
Nonlinear Effect , Helical structure , Helicity control , Chiral carboxylate , zinc complex
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1888660
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