Title of article
Enantiodifferentiating [2+2] photocycloaddition of cyclohexenone carboxylic acid with ethylene using 8-phenylmenthyl amine as a chiral template
Author/Authors
Yanagisawa، نويسنده , , Yuuki and Nishiyama، نويسنده , , Yasuhiro and Tanimoto، نويسنده , , Hiroki and Morimoto، نويسنده , , Tsumoru and Kakiuchi، نويسنده , , Kiyomi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
2123
To page
2126
Abstract
Enantiodifferentiating [2+2] photocycloaddition of cyclohexenone carboxylic acid with the smallest olefin, ethylene, was accomplished using 8-phenylmenthyl amine as a chiral template. Particularly, we succeeded in enhancing the enantiomeric excess (ee) value by selective excitation of a chiral substrate–template supramolecular complex.
Keywords
Chiral template , ethylene , cyclobutane , Enantiodifferentiating
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1888749
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