Title of article :
Enantiodifferentiating [2+2] photocycloaddition of cyclohexenone carboxylic acid with ethylene using 8-phenylmenthyl amine as a chiral template
Author/Authors :
Yanagisawa، نويسنده , , Yuuki and Nishiyama، نويسنده , , Yasuhiro and Tanimoto، نويسنده , , Hiroki and Morimoto، نويسنده , , Tsumoru and Kakiuchi، نويسنده , , Kiyomi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
Enantiodifferentiating [2+2] photocycloaddition of cyclohexenone carboxylic acid with the smallest olefin, ethylene, was accomplished using 8-phenylmenthyl amine as a chiral template. Particularly, we succeeded in enhancing the enantiomeric excess (ee) value by selective excitation of a chiral substrate–template supramolecular complex.
Keywords :
Chiral template , ethylene , cyclobutane , Enantiodifferentiating
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
