Title of article :
Catalytic enantioselective C(sp3)H functionalization: intramolecular benzylic [1,5]-hydride shift
Author/Authors :
Yu، نويسنده , , Jie and Li، نويسنده , , Nan and Chen، نويسنده , , Dian-Feng and Luo، نويسنده , , Shi-Wei، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
The catalytic asymmetric [1,5]-hydride transfer/cyclization sequence involving benzylic C(sp3)H bond was established, providing tetrahydronaphthalene derivatives in moderate to high yield with up to 69% ee, by employing the copper complex of side-armed bisoxazoline as chiral catalyst.
Keywords :
Asymmetric catalysis , 5]-Hydride transfer , 1 , Benzylic C(sp3)H bond , Side-armed bisoxazoline
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
