Title of article :
Regioselective ring-opening α-methylenation of aryl epoxides to conjugated allyl alcohols utilizing n-BuLi and Me2SCH2 reagents
Author/Authors :
Tomioka، نويسنده , , Takashi and Sankranti، نويسنده , , Rambabu and James، نويسنده , , Amber M. and Mattern، نويسنده , , Daniell L. Mattern، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
In the presence of a mixture of n-BuLi and Me2SCH2 reagents, aryl epoxides underwent a novel ring-opening α-methylenation providing conjugated allyl alcohols with an unusual regioselective pattern.
Keywords :
?-Methylenation , Allyl alcohol , Aryl epoxide , Dimethylsulfonium methylide , One-carbon homologation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters