Title of article :
A simple method for desymmetrizing 1,1′-ferrocenedicarboxaldehyde
Author/Authors :
Benniston، نويسنده , , Andrew C. and Sirbu، نويسنده , , Dumitru and Turta، نويسنده , , Constantin and Probert، نويسنده , , Michael R. and Clegg، نويسنده , , William، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
A simple chromatography-free method for desymmetrizing ferrocene is described starting from the readily available dialdehyde. Oxidation of 1,1′-ferrocenedicarboxaldehyde in a water/acetonitrile mixture with KMnO4 produced 1′-formyl-ferrocenecarboxylic acid. The same reaction carried out in a water/acetone mixture produced 1′-[(E)-3-oxo-but-1-enyl]-ferrocenecarboxylic acid.
Keywords :
Oxidation , Carboxylic acid , desymmetrization , Michael addition , Ferrocene
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
