Title of article
New data on heteroarene thiocyanation by anodic oxidation of NH4SCN. The processes of electroinduced nucleophilic aromatic substitution of hydrogen
Author/Authors
Kokorekin، نويسنده , , Vladimir A. and Sigacheva، نويسنده , , Vera L. and Petrosyan، نويسنده , , Vladimir A.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
4306
To page
4309
Abstract
Potentiostatic (galvanostatic) electrolysis of NH4SCN in an undivided cell under mild conditions (25 °C, Pt anode, MeCN) was employed to perform the anodic thiocyanation of nitrogen-containing heterocycles with yields up to 95%. The regularities of the process are discussed, which show that it can be considered as electroinduced nucleophilic aromatic substitution of hydrogen.
Keywords
Anodic thiocyanation , indole , pyrrole , Azole , Cyclic voltammetry
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1890250
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