Title of article :
Stereoselective total synthesis of oplopandiol, oploxyne A, and oploxyne B
Author/Authors :
Reddy، نويسنده , , B.V. Subba and Nageshwar Rao، نويسنده , , R. and Kumaraswamy، نويسنده , , B. and Yadav، نويسنده , , J.S.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2014
Abstract :
A stereoselective total synthesis of oplopandiol, oploxyne A, and (−)-oploxyne B is described. The key reactions include Sharpless asymmetric epoxidation, d-proline catalyzed aminoxylation, Cadiot–Chodkiewicz cross-coupling reaction, m-CPBA induced substrate-controlled stereoselective epoxidation, and Lewis acid catalyzed stereo- and regioselective ring-opening of epoxide.
Keywords :
Cadiot–Chodkiewicz cross-coupling reaction , Ene-diynes , Organocatalyzed aminoxylation , Sharpless asymmetric epoxidation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
