Title of article
Rapid construction of polycyclic ring systems from aromatics: stereoselective synthesis of the carbon framework of vinigrol
Author/Authors
Lu، نويسنده , , Yan-Bin and Hsu، نويسنده , , Day-Shin and Liao، نويسنده , , Chun-Chen، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
4
From page
5315
To page
5318
Abstract
The stereoselective syntheses of the tricyclic core structure of vinigrol and highly functionalized polycyclic molecules from 5-bromo-2-methoxyphenol in five synthetic steps are reported. Intramolecular and intermolecular Diels–Alder reactions and tandem oxy-Cope/ene reactions are the key steps in the synthesis.
Keywords
Ene reaction , Masked o-benzoquinones , oxy-Cope rearrangement , Tandem reaction , Polycycles
Journal title
Tetrahedron Letters
Serial Year
2014
Journal title
Tetrahedron Letters
Record number
1890716
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