Author/Authors :
Minicone، نويسنده , , Fabrizio and Rogers، نويسنده , , Wendy J. and Green، نويسنده , , James F.J. and Khan، نويسنده , , Mommna and Smith، نويسنده , , Geoffrey M.T. and Bray، نويسنده , , Christopher D.، نويسنده ,
Abstract :
Treatment of terminal epoxides with N-arylphosphoramidate anions leads directly to N-aryl aziridines. Existing methods for this transformation employ either multi-step syntheses or an iminophosphorane in conjunction with a Lewis acid. The described method therefore presents an advantage in terms of brevity and atom economy.
Keywords :
aziridine , epoxide , phosphoramidate , ring-opening , Anion-relay
